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Mathematical Tripos Part 1B Dr. Eugene A. Lim

Michaelmas Term 2012 eal40@damtp.cam.ac.uk

QUANTUM MECHANICS

Lecturer: Dr. Eugene A. Lim

Michaelmas 2012

Office : DAMTP B2.09

http://www.damtp.cam.ac.uk/user/eal40/teach/QM2012/QMroot.html

Introduction : Quantum Mechanics with QubitsThe Postulates of Quantum Mechanics for Qubits. Dynamics of Qubits.

The Failure of Classical Mechanics and Wave-Particle DualityThe Classical Wave Equation. Double Slit Experiment. Photoelectric Effect. Wave-Particle Duality.

The Mathematics of Quantum MechanicsThe Postulates of Quantum Mechanics. Operators. Eigenfunctions and Eigenvalues. Observables

and Hermitian Operators.

Schrodingers EquationDynamics of Non-relativistic Particles. Principle of Superposition. Probability Current. Free

Particles. Degeneracies. Stationary States.

Solving Schrodingers Equation in One DimensionQuantization of bound states. Scattering and Tunneling. The Gaussian Wavepacket. Parity Oper-

ator.

The Simple Harmonic OscillatorQuantization in Position Basis. *Quantization in Energy Basis.

Commutators, Measurement and The Uncertainty PrincipleExpectation Values. Commutators and Measurements. Simultaneous Eigenfunctions. The Uncer-

tainty Principle.

The Hydrogen AtomThe Bohr Model. Schrodingers Equation in Spherical Coordinates. S-waves of Hydrogen Atom.

Angular Momentum. The Full Spectrum of Hydrogen Atom.

*Epilogue : Love and Quantum MechanicsEntanglement. Teleportation.

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Recommended Books

S. Gasiorowicz, Quantum Physics, Wiley 2003.

R. Shankar,Principles of Quantum Mechanics, Kluwer 1994.

R. P. Feynman, R. B. Leighton and M. Sands, The Feynman Lectures on Physics, Volume 3,Addison-Wesley 1970.

P. V. Landshoff, A. J. F. Metherell and W. G. Rees, Essential Quantum Physics, CambridgeUniversity Press 1997.

P. A. M. Dirac, The Principles of Quantum Mechanics, Oxford University Press 1967, reprinted2003.

J. J. Sakurai, J. Napolitano, Modern Quantum Mechanics, Addison-Wesley 2011

Acknowledgements

Firstly, thanks to Prof. David Tong and Prof. Anne Davis for advice and words of wisdom when I taught

this class last year. Also thanks to the students of Part IB QM 2011 Michaelmas who had to sit through

my lectures and gave a lot of feedback. Finally and most importantly, many thanks to Prof. Nick Dorey

who provided much advice and whose lecture notes of the same class these notes are based on. No cats

were harmed during the production of these notes.

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1 Introduction : Quantum Mechanics with Qubits

This is Serious Thread.

Serious Cat

When you studied Classical Mechanics in the Dynamics and Relativity lectures last year, you were

told that a particle is an object of insignificant size. Then you spent eight weeks studying the dynamics

of this particle and took an exam. One of the things you learned is to describe the state of the particle

in terms of its position x and momentum p (and given its mass m, one can deduce its velocity x = p/m),

both which take definite real values at any given moment in time.

Lets think about a non-relativistic particle of mass m. In many of the problems and calculations,

you often assumed that once you know information of these two variables (x(t0), p(t0)) of this particle at

some initial time t0, using Newtons Laws of Motion,

dp

dt= F (1)

you can calculate and predict to any arbitrary accuracy the position and momentum (x(t), p(t)) of this

particle at some later time t > t0. In addition, it is implicit that one can at any time measure with

arbitary accuracy the values of variables as we please.

In words we say that we know the state of the particle at any time t. The key phrases we have

used in the above description is Classical Mechanics and arbitrary accuracy. It turns out that, in

Quantum Mechanics, one of the ideas that we have to abandon is the notion that we can predict to any

arbitrary accuracy the position and momentum of any particle. In fact, it is worse than this: another

notion we have to abandon is the idea of that we can measure with arbitrary accuracy both variables at

the same time t. These two notions are not only those we will abandon of course, but giving these up

already begs a bunch of questions: How do we describe the state of a particle, and how do we describe

its dynamics?

Hence, in the study of how quantum particles move, or more generally how dynamical systems behave:

rocks, electrons, Higgs Bosons, cats, you name it, we have to start with an entire new notion of how

dynamical states of systems are described mathematically. Indeed, once we give up the notion of absolute

knowledge about the state, we can start to introduce even more abstract states which has no classical

analog such as the spin of an electron, and even more abstractly, how information is encoded in quantum

mechanical systems.

In this first section of the lectures, we will use the simplest possible dynamical system a system

with only two possible states as an introduction into the weird world of Quantum Mechanics. The

goal of this introduction is to give you a broad overview of the structure of Quantum Mechanics, and to

introduce several new concepts. Dont worry if you dont follow some of the details or you find that there

are a lot of unexplained holes, we will go over the same ground and more in the coming lectures.

1.1 Classical Bit vs Quantum Qubit

As children of the computer revolution, you must be familiar with the idea of a bit of information. The

bit is a system that can only has two possible states: 1/0 or up/down or on/off or dead cat/live cat etc.

Lets use up/down for now. Such binary systems are also called (obviously) two-state systems. We can

endow this bit with some set of physical rules which when acted upon the system, may change it from one

state to another. For example, in Newtons Law of motion, the dynamics of (x, p) are described by Eq.

(1). In words it means When we act on the particle with a force described by F (x) for an infinitisimal

time dt, the value of p changes by Fdt. What kind of rules can we write down for a bit?

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INPUT OUTPUT

down up

up down

Table 1: A NOT gate

The set of rules for a bit can be something simple like a NOT gate. This rule simply flips an up to a

down, and a down to an up. A NOT gate rule is shown in Table 1. Another rule we can write down is

the do nothing gate, which just returns up if acted on up, and down if acted on down.

Mathematically, we can define the following column matrices to represent the up/down states

up =

(1

0

), down =

(0

1

), (2)

so a NOT gate can be described by the 2 2 matrix

P =

(0 1

1 0

), (3)

while a do nothing gate is obviously the identity

I =

(1 0

0 1

). (4)

Acting then means usual matrix multiplication of the column vector from the left by the gate matrix

result = gate matrix state. (5)

You can check that acting from the left with P and I on an up/down state gets you the right results,

e.g. acting on up state with NOT gate yields a down state

down = Pup. (6)

A bit is a classical quantity, so we can measure with arbitrary accuracy whether it is up or down. For

example, a classical cat is either dead or alive (just check its pulse). We can also predict with arbitrary

accuracy what would happen when we act on the bit with the rules: if we start with a up, acting on it

with a NOT gate we predict that it will become a down (and then we can measure it to confirm that our

prediction is true).

What about a quantum two-state system? Such a quantum state is called a qubit, for quantum bit

obviously. What are the properties of a qubit and what kind of real physical system is modeled by one?

You might have heard about the sad story of Schrodingers Cat. The cat is put inside a closed box. There

is a vial of poison gas in the box. A hammer will strike the vial if a certain amount of radioactivity is

detected in the box, thus killing the cat. An observer outside the box has no way of finding out if this

sad affair has occured without opening the box. Hence the cat is in the curious state of being both alive

and dead at the same time according to the observer: the information about the deadness or aliveness of

the cat is carried by a qubit.

You probably have realized that I have shoved a ton of things under a carpet of words here, and words

are not well defined there are many equally good ways to implement those words but Nature chose the

path of Quantum Mechanics. Lets now be a bit more precise, and introduce the Postulates of Quantum

Mechanics for two-state systems. We will elaborate on each of these postulates for more general cases in

future lectures.

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Figure 1: Schrodingers Cat and its sad/happy fate. Stolen from Wikipedia.

Postulate 1 (State): A qubit, , is described by the state vector

= up + down , where , C. (7)

and are called probability amplitudes for finding the up and down state, for reasons we will soon

see. The important point here is that the coefficients and are complex numbers this means that the

information encoded in the state has been enlarged when compared to the binary classical bit1. Postulate

1 tells us that the state can be neither up nor down; it is some linear superposition beteween two